Removal of Nickel Ion From synthesis wastewater Using Nanoparticles Under Ultrasonic Waves
DOI:
https://doi.org/10.31185/wjes.Vol14.Iss2.827Keywords:
Ultrasonic Waves, Fe3O4 nanoparticle, Nickel (II), Heavy MetalsAbstract
One of the most significant pollutants released into the environment by industrial processes is heavy metals. The adsorption technique has emerged as a leading strategy for metal ion removal in the last several years. The mass transfer process can be enhanced with the help of ultrasound. This study examined the effectiveness of high frequency ultrasonic waves in increasing the absorption of nickel (II) in aqueous solutions containing Fe3O4 nanoparticles. A higher initial amount of adsorbent was associated with a higher removal efficiency of nickel (II). When comparing the effectiveness of using shakers and an ultrasonic test vessel, the latter achieved a maximum efficiency of 84.3% at 60 minutes of contact time, 8 g of adsorbent at pH=5, while the former performed better. On the other hand, while using a shaker and 100 minutes of contact time with 10 g of adsorbent and pH=9, the greatest efficiency was 54.79%. Looking at how contact time affected the adsorption rate, we found that it was fastest at the beginning of the contact period. Increasing the contact duration and equilibrium time resulted in an increase in the amount of nickel (II) elimination from 20 minutes to 60 minutes when using either a shaker or a test vessel. But when using a shaker, the nickel (II) removal rate spiked again between the 60-minute and 80-minute contact times, reaching a peak of 79.54% in the latter. Actually, cavitacin and high-frequency ultrasonic waves can produce microcurrents that remove a large amount of nickel (II) from water in a very short amount of time. A modest quantity of adsorbent was able to achieve a rapid increase in absorption rate when ultrasonic waves were introduced into the test vessel.
References
[1]. C. Buzea, I. I. Pacheco Blandino, and K. Robbie, "Nanomaterials and nanoparticles: Sources and toxicity," Biointerphases, vol. 2, pp. 17-172, 2007.
[2]. G. Cao, Nanostructure & Nanomaterials: Synthesis, Properties & Applications, Imperial College Press, London, 2004.
[3]. R. Wang, B. G. Li, T. Huang, and L. Shi, "NbCl5-Catalyzed one-pot Mannich-type reaction: three component synthesis of β-amino carbonyl compounds," Tetrahedron Lett., vol. 48, pp. 2071-2073, 2007.
[4]. Y. Yoichi, A. Yamada, and Y. Uozumi, "Development of a convoluted polymeric nanopalladium catalyst: α-alkylation of ketones and ring-opening alkylation of cyclic 1,3-diketones with primary alcohols," Tetrahedron Lett., vol. 63, pp. 8492-8498, 2007.
[5]. W. Jiang, Y. Zhou, Y. Zhang, S. Xuanb, and X. Gong, "Superparamagnetic Ag@Fe3O4 core–shell nanospheres: fabrication, characterization and application as reusable nanocatalysts," Dalton Trans., vol. 41, pp. 4594-4601, 2012.
[6]. C.-J. Zhong and M. Maye, "Core-Shell assembled nanoparticles as catalysts," Adv. Mater., vol. 13, pp. 1507-1511, 2001.
[7]. U. S. Choi, "Enhancing thermal conductivity of fluids with nanoparticles," ASME FED, vol. 231, pp. 99-103, 1995.
[8]. A. K. Gupta and M. Gupta, "Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications," Biomaterials, vol. 26, pp. 3995-4021, 2005.
[9]. P. Hajiani and F. Larachi, "Controlling lateral nanomixing and velocity profile of dilute ferrofluid capillary flows in uniform stationary, oscillating and rotating magnetic fields," Chem. Eng. J., vol. 223, pp. 454-466, 2013.
[10]. Q. Li and Y. Xuan, "Experimental investigation on heat transfer characteristics of magnetic fluid flow around a fine wire under the influence of an external magnetic field," Exp. Therm Fluid Sci., vol. 33, pp. 591-596, 2009.
[11]. M. N. Rashin and J. Hemalatha, "Magnetic and ultrasonic studies on stable cobalt ferrite magnetic nanofluid," Ultrasonics, vol. 54, pp. 834-840, 2014.
[12]. F. Larachi and D. Desvigne, "Ferrofluid induced-field effects in inhomogeneous porous media under linear-gradient DC magnetic fields," Chem. Eng. Process., vol. 46, pp. 729-735, 2007.
[13]. G.-P. Zhu and N.-T. Nguyen, "Rapid magnetofluidic mixing in a uniform magnetic field," Lab Chip, vol. 12, pp. 4772-4780, 2012.
[14]. M. Mahdavi, M. B. Ahmad, M. J. Haron, F. Namvar, B. Nadi, M. Z. A. Rahman, et al., "Synthesis, surface modification and characterisation of biocompatible magnetic iron oxide nanoparticles for biomedical applications," Molecules, vol. 18, pp. 7533-7548, 2013.
[15]. N.-T. Nguyen, "Micro-magnetofluidics: interactions between magnetism and fluid flow on the microscale," Microfluid Nanofluidics, vol. 12, pp. 1-16, 2012.
[16]. Z. Yuanbi, Q. Zumin, and J. Huang, "Preparation and analysis of Fe3O4 magnetic nanoparticles used as targeted-drug carriers," Chin. J. Chem. Eng., vol. 16, pp. 451-455, 2008.
[17]. Y.-J. Chang, C.-Y. Hu, and C.-H. Lin, "A microchannel immunoassay chip with ferrofluid actuation to enhance the biochemical reaction," Sens. Actuator B-Chem., vol. 182, pp. 584-591, 2013.
[18]. G.-P. Zhu and N.-T. Nguyen, "Magnetofluidic spreading in microchannels," Microfluid Nanofluidics, vol. 13, pp. 655-663, 2012.
[19]. Y. Bulut and H. Aydin, "A kinetic and thermodynamics study of methylene blue adsorption on wheat shells," Desalination, vol. 194, pp. 259-267, 2006.
[20]. Y. C. Chang and D. H. Chen, "Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu (II) ions," J. Colloid Interface Sci., vol. 283, pp. 446-461, 2005.
[21]. M. Galamboš, O. Rosskopfová, J. Kufčáková, and P. Rajec, "Utilization of Slovak bentonites in deposition of high-level radioactive waste and spent nuclear fuel," 288(3), pp. 765-777, 2011.
[22]. T. K. Das, "Disinfection," in Kirk-Othmer Encyclopedia of Chemical Toxicology, John Wiley & Sons, Inc., vol. 8, pp. 605-672, 2002.
[23]. D. Dickson, G. Liu, Ch. Li, G. Tachiev, and Y. Cai, "Dispersion and stability of bare hematite nanoparticles: Effect of dispersion tools, nanoparticle concentration, humic acid and ionic strength," Sci. Total Environ., vol. 419, pp. 170-177, 2012.
[24]. S. Singh, K. C. Barick, and Bahadur, "Functional oxide nanomaterials and nanocomposites for the removal of heavy metals and dyes," J. Nanosci. Nanotechnol., vol. 3, pp. 1-19, 2013.
[25]. M. Hua, Sh. Zhang, B. Pan, W. Zhang, L. L. Quanxing Zhang, "Heavy metal removal from water/wastewater by nanosized metal oxides: A review," J. Hazard. Mater., vol. 211, pp. 317-331, 2012.
[26]. R. Prucek, J. Tucek, M. Kilianová, A. Panácek, L. Kvítek, J. Filip, M. Kolár, K. Tománková, and Z. R. Zboril, "The targeted antibacterial and antifungal properties of magnetic nanocomposite of iron oxide and silver nanoparticles," Biomaterials, vol. 32, pp. 4704-4713, 2011.
[27]. R. J. Smialowicz, R. R. Rogers, M. M. Riddle, and G. A. Scott, "Immunologic effects of nickel: I. Suppression of cellular and humoral immunity," Environmental Research, vol. 33, pp. 413-427, 1984.
[28]. Z. T. Hafez, "The role of microstreaming in ultrasound-enhanced thrombolysis," M.Sc. thesis, University of Illinois at Urbana-Champaign, 2008.
[29]. M. D. Luque de Castro and F. Priego Capote, Analytical Applications of Ultrasound, 1st ed., Elsevier Publisher, Spain, 2007.
[30]. M. Matouq and Z. Anber, "The application of high frequency ultrasound waves to remove ammonia from simulated industrial wastewater," Ultrasonics Sonochemistry, vol. 14, pp. 393-397, 2007.
[31]. N. P. Dhanalakshmi, R. Nagarajan, N. Sivagaminathan, and B. V. S. S. Prasad, "Acoustic enhancement of heat transfer in furnace tubes," Chemical Engineering and Processing, vol. 59, pp. 36-42, 2012.
[32]. L. H. Thompson and L. K. Doraiswamy, "The rate enhancing effect of ultrasound by inducing supersaturation in a solid–liquid system," Chemical Engineering Science, vol. 55, pp. 3085-3090, 2000.
[33]. T. K. Jagannathan, R. Nagarajan, and K. Ramamurthi, "Effect of ultrasound on bubble breakup within the mixing chamber of an effervescent atomizer," Chemical Engineering and Processing, vol. 50, pp. 305-315, 2011.
[34]. J. A. Cárcel, J. V. García-Pérez, J. Benedito, and A. Mulet, "Food process innovation through new technologies: Use of ultrasound," Journal of Food Engineering, vol. 110, pp. 200-207, 2012.
[35]. D. W. Zhou, D. Y. Liu, X. G. Hu, and C. F. Ma, "Effect of acoustic cavitation on boiling heat transfer," Experimental Thermal and Fluid Science, vol. 26, pp. 931-938, 2002.
[36]. M. Lim, Y. Son, and J. Khim, "Frequency effects on the sonochemical degradation of chlorinated compounds," Ultrasonics Sonochemistry, vol. 18, pp. 460-465, 2011.
[37]. J. Bao, Y. Fu, and Z. Bao, "Thiol-functionalized magnetite/graphene oxide hybrid as a reusable adsorbent for Hg2+ removal," Nanoscale Res. Lett., vol. 8, pp. 1-6, 2013.
[38]. J. U. Lee, W. Lee, J. W. Yi, S. S. Yoon, S. B. Lee, B. M. Jung, B. S. Kim, J. H. Byun, "Preparation of highly stacked graphene papers via site-selective functionalization of graphene oxide," J. Mater. Chem. A, vol. 1, pp. 12893-12899, 2013.
[39]. K. S. Suslick, Y. Didenko, M. M. Fang, T. Hyeon, K. J. Kolbeck, W. B. McNamara, M. M. Mdleleni, and M. Wong, "Acoustic cavitation and its chemical consequences," Phil. Trans. R. Soc. Lond. A, vol. 357, pp. 335-353, 1999.
[40]. C. Selomulya, V. Meeyoo, and R. Amal, "Mechanisms of Cr(VI) removal from water by various types of activated carbons," J. Chem. Technol. Biotechnol., vol. 74, pp. 111-122, 1999.
[41]. N. R. Bishnoi, M. Bajaj, N. Sharma, and A. Gupta, "Adsorption of Cr(VI) on activated rice husk carbon and activated alumina," Bioresource Technology, vol. 305-307, 2004.
[42]. T. Karthikeyan, S. Rajgopal, and L. R. Miranda, "Chromium(VI) adsorption from aqueous solution by Hevea brasilinesis sawdust activated carbon," Journal of Hazardous Materials, pp. 192–199, 2005.
[43]. H. Demiral, I. Demiral, F. Tumsek, and B. Karabacakoglu, "Adsorption of chromium(VI) from aqueous solution by activated carbon derived from olive bagasse and applicability of different adsorption models," Chemical Engineering, pp. 188-196, 2008.
[44]. M. H. Fatehi, J. Shayegan, M. Zabihi, and I. Goodarznha, "Functionalized magnetic nanoparticles supported on activated carbon for adsorption of Pb(II) and Cr(VI) ions from saline solutions," Environmental Chemical Engineering, vol. 5, pp. 1754-1762, 2017.
[45]. G. Jing, Z. Zhou, L. Song, and M. Dong, "Ultrasound enhanced adsorption and desorption of chromium (VI) on activated carbon and polymeric resin," Desalination, vol. 279, pp. 423-427, 2011.
[46]. O. Lacin, Ö. Korkut, E. Sayan, and B. Bayrak, "Investigation of adsorption and ultrasound assisted desorption of lead (II) and copper (II) on local bentonite: A modelling study," Desalination, vol. 259, pp. 243-248, 2010.
[47]. M. Ghaedi, A. Asfaram, S. Hajati, A. Goudarzi, and A. A. Bazrafshan, "Simultaneous ultrasound-assisted ternary adsorption of dyes onto copper-doped zinc sulfide nanoparticles loaded on activated carbon: Optimization by response surface methodology," Spectrochim. Acta A, vol. 151, pp. 215-222, 2015.
[48]. F. S. P. Franco, J. M. Cunha, G. F. Dortzbacher, and G. L. Dotto, "Adsorption of Co(II) from aqueous solutions onto rice husk modified by ultrasound assisted and supercritical technologies," Process Safety and Environment Protection, vol. 101, pp. 91-98, 2017.
[49]. R. Zare-Dorabei, S. Moazen Ferdowsi, A. Barzin, and A. Tadjarodi, "Highly efficient simultaneous ultrasonic-assisted adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) ions from aqueous solutions by graphene oxide modified with 2,2'-dipyridylamine: Central composite design optimization," Ultrason. Sonochem., vol. 31, pp. 265-272, 2016.
[50]. Ö. Korkut, E. Sayan, O. Lacin, and B. Bayrak, "Investigation of adsorption and ultrasound assisted desorption of lead (II) and copper (II) on local bentonite: A modelling study," Desalination, vol. 259, pp. 243-248, 2010.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Nuralhuda Aladdin Jasim, Walaa Abdulkhaleq Zghair, Manal Abdulsattar Muhammed, Ahmed Muhammad Dakhil, Kamaludin Mohamad Yusof

This work is licensed under a Creative Commons Attribution 4.0 International License.

