Color and COD Removal from Textile Effluent by Advanced Oxidation Processes (ozonation)
DOI:
https://doi.org/10.31185/wjes.Vol14.Iss2.694Keywords:
AOPS, texitle, effluent, COD, color, turbidity, and wastewater treatment.Abstract
Using an ozone reactor, this work looks at how well ozonation removes turbidity, COD, and methylene blue dyes from polluted water. The main goals were to assess ozonation's efficacy in degrading methylene blue dyes, lowering COD, and clearing turbidity, and to find the ideal reaction time for the best removal efficiency.
The findings showed that ozonation greatly enhanced the removal of turbidity, color, and COD over time. Ozonation 1 (10%) had the least efficiency in terms of COD removal, with about 30% removal at 180 minutes; the others, Ozonation 2 (20%) and Ozonation 5 (50%) had 55% and 60% removals, respectively. Ozonation 1 removed 50% of the turbidity; ozonation 2 and ozonation 5 showed the greatest efficiency with 75% and 78% elimination at 180 minutes, respectively. Ozonation 1 removed around 50% of the color; Ozonation 2 and Ozonation 5 removed 70% at the same reaction time; thus, the color removal also rose markedly. After 180 minutes, Ozonation 4 (40%) exhibited moderate effectiveness with COD, turbidity, and color removal reaching 70%, 70%, and 75%, respectively. This work shows that higher removal efficiencies for COD, color, and turbidity are significantly influenced by prolonged reaction periods. Particularly for Ozonation 2 and Ozonation 5, the custom-built ozone reactor was successful in optimizing ozone settings, which produced the best overall outcomes in eliminating methylene blue dyes, COD, turbidity, and color.
References
[1] T. Robinson, G. McMullan, R. Marchant, and P. Nigam, "Remediation of dyes in textile effluent: A critical review on current treatment technologies with a proposed alternative," Bioresource Technology, vol. 77, no. 3, pp. 247–255, 2001. https://doi.org/10.1016/S0960-8524(00)00080-8.
[2] H. Zollinger, Color Chemistry: Syntheses, Properties, and Applications of Organic Dyes and Pigments, 3rd ed. Wiley-VCH, 2003.
[3] E. Forgacs, T. Cserháti, and G. Oros, "Removal of synthetic dyes from wastewaters: a review," Environment International, vol. 30, no. 7, pp. 953–971, 2004. https://doi.org/10.1016/j.envint.2004.02.001.
[4] D. A. Yaseen and M. Scholz, "Textile dye wastewater characteristics and constituents of synthetic effluents: A critical review," Int. J. Environ. Sci. Technol., vol. 16, pp. 1193–1226, 2019.
[5] R. Andreozzi, V. Caprio, A. Insola, and R. Marotta, "Advanced oxidation processes (AOP) for water purification and recovery," Catalysis Today, vol. 53, no. 1, pp. 51–59, 1999. https://doi.org/10.1016/S0920-5861(99)00102-9.
[6] B. Kasprzyk-Hordern, U. Raczyk-Stanisławiak, and J. Nawrocki, "Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment," Appl. Catal. B: Environ., vol. 46, no. 4, pp. 639–669, 2003. https://doi.org/10.1016/S0926-3373(03)00215-1.
[7] W. G. Kuo, "Decolorizing dye wastewater with Fenton’s reagent," Water Res., vol. 26, no. 7, pp. 881–886, 1992. https://doi.org/10.1016/0043-1354(92)90127-Z.
[8] S. Esplugas, D. M. Bila, L. G. T. Krause, and M. Dezotti, "Ozonation and advanced oxidation technologies to remove endocrine disrupting chemicals (EDCs) and pharmaceuticals and personal care products (PPCPs) in water effluents," J. Hazard. Mater., vol. 149, no. 3, pp. 631–642, 2007. https://doi.org/10.1016/j.jhazmat.2007.07.073.
[9] P. Asaithambi et al., "Removal of Color and COD from Wastewater Using the Combined Fenton Oxidation Process (Fe²⁺/H₂O₂) and Ozone Oxidation (O₃)," J. Environ. Manage., 2022.
[10] M. Asghar, A. Jamal, S. Khan, and U. Shafique, "Catalytic ozonation of textile wastewater using MCC@ZIF-67: Enhanced degradation performance under optimized conditions," Sci. Total Environ., vol. 909, 170072, 2025. https://doi.org/10.1016/j.scitotenv.2025.170072.
[11] P. Kumar and S. Rani, "Treatment of textile dyeing wastewater using combined Fenton and ozonation processes: Effect of pH on removal efficiency," Environ. Sci. Pollut. Res., 2025. https://doi.org/10.1007/s44373-025-00017-x.
[12] H. Saleem, M. Latif, M. Usman, and M. Rafique, "Hybrid treatment of textile wastewater using catalytic ozonation and electrocoagulation enhanced by ZIF-67 catalyst," Environ. Nanotechnol. Monit. Manage., vol. 23, 100836, 2025. https://doi.org/10.1016/j.enmm.2024.100836.
[13] M. Fernández, P. Torres, V. Romero, and C. Lozano, "Innovative sustainable solutions for detoxifying textile effluents using advanced oxidation and biological processes: A review," Sci. Total Environ., vol. 911, 170807, 2025. https://doi.org/10.1016/j.scitotenv.2025.170807.
[14] D. Yildiz, D. Karadag, and F. Tokatli, "Investigation of color and COD removal from real textile wastewater using anaerobic treatment followed by ozonation as post-treatment," ResGate Preprint, 2025. https://www.researchgate.net/publication/287299770.
[15] S. Ahamad, S. Nanda, and P. Kumar, "Optimization of Ozonation Process for Wastewater Treatment: Removal of COD, BOD, and Other Pollutants," J. Environ. Chem. Eng., vol. 8, no. 5, 104456, 2020.
[16] L. Hu, Q. Xu, Z. Zhang, and Z. Li, "Enhanced COD Removal from Textile Wastewater Using Ozonation: Role of Ozone Dose and Reaction Time," Water Res., vol. 150, pp. 110-120, 2019.
[17] Y. Lee, Y. Park, and H. Kim, "A Study on Ozonation for Removal of COD in Industrial Wastewater," J. Hazard. Mater., vol. 357, pp. 94-102, 2018.
[18] G. G. El-Din, "Ozone-Based Advanced Oxidation Processes for Wastewater Treatment: Optimization of Operational Parameters," Chem. Eng. J., vol. 306, pp. 472-481, 2017.
[19] X. Xu, X. Wang, and Z. Chen, "The Effectiveness of Ozonation on COD Removal from Various Types of Industrial Wastewater," Environ. Sci. Pollut. Res., vol. 27, no. 5, pp. 5517-5525, 2020.
[20] P. Bajpai, "Ozonation and Advanced Oxidation Processes for Industrial Wastewater Treatment," Ind. Wastewater Treat., vol. 3, no. 1, pp. 75-85, 2015.
[21] M. Rajkumar and P. Sivakumar, "Ozone and UV-Ozone Assisted Wastewater Treatment for Color and Turbidity Removal," J. Environ. Manage., vol. 238, pp. 174-183, 2019.
[22] Y. Lee, Y. Park, and H. Kim, "A Study on Ozonation for Removal of Color and COD in Industrial Wastewater," J. Hazard. Mater., vol. 357, pp. 94-102, 2018.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Saja Hamed, Ali Jwaid

This work is licensed under a Creative Commons Attribution 4.0 International License.

