Adsorption Study for the Removal of Cadmium and Lead from Synthetic Storm Water Using Fired Clay

Authors

  • Khirat yunis Wasit university
  • Ali J. Jaeel

DOI:

https://doi.org/10.31185/ejuow.Vol12.Iss3.468

Keywords:

Stormwater, cadmium, lead, adsorption, fired clay.

Abstract

Abstract

  • This work focuses on employing burned clay (FC) materials as a low-cost adsorbent to remove cadmium and lead ions from synthetic stormwater and to evaluate its performance and applicability as a supplementary component to remove Cadmium and Lead ions in an aqueous solution. The studies were carried out to look into the Cadmium and Leads' room-temperature adsorption isotherm and the effects of various variables. The primary adsorbate concentration, contact time, agitation speed, pH, and mass of the adsorbent have all been studied. According to the results, the optimal experimental conditions-pH=6, 0.45mg/l of Cadmium and 0.08 mg/L of Lead as adsorbate, 12 g of adsorbent, 250 rpm of agitation, and 2.0 hours of contact time -reduced Cadmium and Lead by 93 percent for fired clay. The experimental data were examined using the Langmuir and Frendlich isotherm models. The preferred model for Cadmium and Lead adsorption onto fired clay material, according to the results, was the Langmuir adsorption isotherm. This study clearly shows that fired clay particles can be employed as a low-cost adsorbent to take Cadmium and Lead out of water.

References

O. H. Adedeji and O. O. Olayinka, "Heavy metal concentrations in urban stormwater runoff and receiving stream," Journal of Environment and Earth Science, vol. 3, no. 7, pp. 141-150, 2013.Available: https://www.academia.edu/download/47565548/6384-8429-1-PB.pdf

I. Milovanovic, I. Herrmann, A. Hedström, K. Nordqvist, A. Müller, and M. Viklander, "Synthetic stormwater for laboratory testing of filter materials," Environmental technology, vol. 44, no. 11, pp. 1600-1612, 2023. doi: 10.1080/09593330.2021.2008516

T. M. Haile and M. Fuerhacker, "Simultaneous adsorption of heavy metals from roadway stormwater runoff using different filter media in column studies," Water, vol. 10, no. 9, p. 1160, 2018. doi: 10.3390/w10091160

Y. Han, S. Lau, M. Kayhanian, and M. K. Stenstrom, "Correlation analysis among highway stormwater pollutants and characteristics," Water Science Technology, vol. 53, no. 2, pp. 235-243, 2006. doi: 10.2166/wst.2006.057

D. Wicke et al., "Micropollutants in urban stormwater runoff of different land uses," Water, vol. 13, no. 9, p. 1312, 2021. doi: 10.3390/w13091312

H. Patel, "Batch and continuous fixed bed adsorption of heavy metals removal using activated charcoal from neem (Azadirachta indica) leaf powder," Scientific Reports, vol. 10, no. 1, p. 16895, 2020. doi: 10.1038/s41598-020-72583-6

A. Esmaeili, M. Mobini, and H. Eslami, "Removal of heavy metals from acid mine drainage by native natural clay minerals, batch and continuous studies," Applied Water Science, vol. 9, pp. 1-6, 2019. doi: 10.1007/s13201-019-0977-x

H. A. Alalwan, M. A. Kadhom, and A. H. Alminshid, "Removal of heavy metals from wastewater using agricultural byproducts," Journal of Water Supply: Research Technology-AQUA, vol. 69, no. 2, pp. 99-112, 2020. doi: 10.2166/aqua.2020.133

A. D. Kayode et al., "Clay soil modification techniques for the adsorption of heavy metals in aqueous medium: A review," Int. J. Adv. Res. Chem. Sci, vol. 6, pp. 14-31, 2019. doi: 10.20431/2349-0403.0606003

S. K. Yadav, D. K. Singh, and S. Sinha, "Chemical carbonization of papaya seed originated charcoals for sorption of Pb (II) from aqueous solution," Journal of environmental chemical engineering, vol. 2, no. 1, pp. 9-19, 2014. doi: 10.1016/j.jece.2013.10.019

J. Ai, X. Wu, Y. Wang, D. Zhang, and H. Zhang, "Treatment of landfill leachate with combined biological and chemical processes: changes in the dissolved organic matter and functional groups," Environmental technology, vol. 40, no. 17, pp. 2225-2231, 2019. doi: 10.1080/09593330.2017.1375015

R. Foroutan et al., "Zinc, nickel, and cobalt ions removal from aqueous solution and plating plant wastewater by modified Aspergillus flavus biomass: A dataset," Data in brief, vol. 12, pp. 485-492, 2017. doi: 10.1016/j.dib.2017.04.031

B. S. Zadeh, H. Esmaeili, and R. Foroutan, "Cadmium (II) removal from aqueous solution using microporous eggshell: kinetic and equilibrium studies," Indonesian Journal of Chemistry, vol. 18, no. 2, pp. 265-271, 2018. doi: 10.22146/ijc.28789

K. Mizuta, T. Matsumoto, Y. Hatate, K. Nishihara, and T. Nakanishi, "Removal of nitrate-nitrogen from drinking water using bamboo powder charcoal," Bioresource technology, vol. 95, no. 3, pp. 255-257, 2004. doi: 10.1016/j.biortech.2004.02.015

R. Mahmudov and C. P. Huang, "Selective adsorption of oxyanions on activated carbon exemplified by Filtrasorb 400 (F400)," Separation Purification Technology, vol. 77, no. 3, pp. 294-300, 2011. doi: 10.1016/j.seppur.2010.12.019

A. Özer, M. Tanyildizi, and F. Tümen, "Study of cadmium adsorption from aqueous solution on activated carbon from sugar beet pulp," Environmental technology, vol. 19, no. 11, pp. 1119-1125, 1998. doi: 10.1080/09593331908616770

A. K. Bhattacharya and C. Venkobachar, "Removal of cadmium (II) by low cost adsorbents," Journal of Environmental Engineering, vol. 110, no. 1, pp. 110-122, 1984. doi: 10.1061/(asce)0733-9372(1984)110:1(110).

Z. Talip, M. Eral, and Ü. Hiçsönmez, "Adsorption of thorium from aqueous solutions by perlite," Journal of Environmental Radioactivity, vol. 100, no. 2, pp. 139-143, 2009. doi: 10.1016/j.jenvrad.2008.09.004

M. A. Hashem, "Adsorption of lead ions from aqueous solution by okra wastes," International Journal of Physical Sciences, vol. 2, no. 7, pp. 178-184, 2007.Available: http://www.academicjournals.org/article/article1380211789_Hashem.pdf

P. Patnukao, A. Kongsuwan, and P. Pavasant, "Batch studies of adsorption of copper and lead on activated carbon from Eucalyptus camaldulensis Dehn. bark," Journal of environmental sciences, vol. 20, no. 9, pp. 1028-1034, 2008. doi: 10.1016/S1001-0742(08)62145-2

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Published

2024-08-01

Issue

Section

Environmental Engineering

How to Cite

yunis, K., & J. Jaeel, A. (2024). Adsorption Study for the Removal of Cadmium and Lead from Synthetic Storm Water Using Fired Clay. Wasit Journal of Engineering Sciences, 12(3), 1-14. https://doi.org/10.31185/ejuow.Vol12.Iss3.468